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exception is tungsten (qv), which can be machined only in strong alkali. the only practical electrolytes are neutral salt solutions in which a metal ion precipitates as a sludge. the most universally used salt in naci because of its availability and low cost. to reduce the ir drop in the gap, strong
the iron (ferric) state in these baths, in an appreciable concentration, is undesirable because it lowers the cathode efficiency for depositing the metal and it may cause deposits to be brittle, stressed and pitted. in practice it is not difficult to maintain the concentration of iron ion at a harmless...
https://niir.org/books/book/handbook-on-electroplating-with-manufacture-electrochemicals/isbn-9788178331706/zb,,18bac,a,0,0,a/index.html