Aqueous solutions

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(tu) and -diazinane- -thione ligands was investigated. the progress of these reactions was monitored by nmr ( h, c, and n) and uv–vis spectroscopy as well as square wave stripping voltammetry. the kinetic studies of the substitution reactions between the above-mentioned complexes with thiones in aqueous

solutions containing mm kcl, which is used to suppress the hydrolysis of the chloride complexes, were conducted. these reactions were followed under pseudo–first-order conditions as functions of ligand concentration, ph, and temperature. the activation parameters (δh#, δs#) were calculated from eyring...

https://www.researchgate.net/publication/332546107_Ni-thiosaccharinate_complexes_Synthesis_characterization_and_DFT_studies_Biological_properties_as_superoxide_dismutase_mimetics_and_as_anti-carcinogenic_agents