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dioxide gas formed by reacting water and isocyanate the balance between gellation and blowing is sensitive to operating parameters including the concentrations of water and catalyst. the reaction to generate carbon dioxide involves water reacting with an isocyanate first forming an unstable carbamic acid

, which then decomposes into carbon dioxide and an amine. the amine reacts with more isocyanate to give a substituted urea. water has a very low molecular weight , so even though the weight percent of water may be small, the molar proportion of water may be high and considerable amounts of urea produced...

https://en.wikipedia.org/wiki/Polyurethane

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