Aqueous solutions

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tertiary amines are more basic than secondary amines, which are more basic than primary amines, and finally ammonia is least basic. the order of pkb's (basicities in water) does not follow this order. similarly aniline is more basic than ammonia in the gas phase, but ten thousand times less so in aqueous

the tricyclics are grouped by the nature of the final amine group on the side chain.) substituted tryptamines and phenethylamines are key basic structures for a large variety of psychedelic drugs . opiate analgesics such as morphine , codeine , and heroin are tertiary amines. gas treatment[ edit ] aqueous...

https://en.wikipedia.org/wiki/Amino_group

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