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with other alkoxides or self-condense to produce a siloxane bond and water. when an acid catalyst is used, protonation of the alkoxysilane increases the reactivity of the leaving group. when a base catalyst is used, deprotonation of the silanol forms a reactive silonate anion. the by-product of the reaction...
with other alkoxides or self-condense to produce a siloxane bond and water. when an acid catalyst is used, protonation of the alkoxysilane increases the reactivity of the leaving group. when a base catalyst is used, deprotonation of the silanol forms a reactive silonate anion. the by-product of the reaction...
of the acetylated glucopyranosyluronate bromide with the nucleophile cyanoethylthioundecahydro-closo-dodecaborate( −). after removal of the cyanoethyl-group, deacetylation and saponification of the reaction product tris(tetramethylammonium)-[s-(β-d-glucuronate)-thio] undecahydro-closo-dodecaborate(...