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vaporization of a cryogenic liquid, except oxygen, in an enclosed area can cause asphyxiation by displac- ing the air. vaporization of liquid oxygen in an enclosed area can cause oxygen enrichment, which could saturate combustibles in the area such as workers' clothing. this can cause a fire if an ignition
when ignited by a spark or even a me- chanical shock are oil, grease, asphalt, kerosene, cloth, tar, and dirt that may contain oil or grease. if liquid oxygen spills on asphalt or other surfaces contaminated with combustibles, do not walk on or roll equipment over the spill area. keep sources of ignition...
http://www.airproducts.com/~/media/Files/PDF/company/safetygram-16.pdf